---
title: "History of chemistry"
chunk: 16/20
source: "https://en.wikipedia.org/wiki/History_of_chemistry"
category: "reference"
tags: "science, encyclopedia"
date_saved: "2026-05-05T03:10:38.639255+00:00"
instance: "kb-cron"
---

He also observed that the intensity of radioactivity of a radioactive element decreases over a unique and regular amount of time until a point of stability, and he named the halving time the "half-life". In 1901 and 1902 he worked with Frederick Soddy to prove that atoms of one radioactive element would spontaneously turn into another, by expelling a piece of the atom at high velocity. In 1906 at the University of Manchester, Rutherford oversaw an experiment conducted by his students Hans Geiger (known for the Geiger counter) and Ernest Marsden. In the Geiger–Marsden experiment, a beam of alpha particles, generated by the radioactive decay of radon, was directed normally onto a sheet of very thin gold foil in an evacuated chamber. Under the prevailing plum pudding model, the alpha particles should all have passed through the foil and hit the detector screen, or have been deflected by, at most, a few degrees.
However, the actual results surprised Rutherford. Although many of the alpha particles did pass through as expected, many others were deflected at small angles while others were reflected back to the alpha source. They observed that a very small percentage of particles were deflected through angles much larger than 90 degrees. The gold foil experiment showed large deflections for a small fraction of incident particles. Rutherford realized that, because some of the alpha particles were deflected or reflected, the atom had a concentrated centre of positive charge and of relatively large mass – Rutherford later termed this positive center the "atomic nucleus". The alpha particles had either hit the positive centre directly or passed by it close enough to be affected by its positive charge. Since many other particles passed through the gold foil, the positive centre would have to be a relatively small size compared to the rest of the atom – meaning that the atom is mostly open space. From his results, Rutherford developed a model of the atom that was similar to the Solar System, known as the Rutherford model. Like planets, electrons orbited a central, Sun-like nucleus. For his work with radiation and the atomic nucleus, Rutherford received the 1908 Nobel Prize in Chemistry.

== 20th century ==

In 1903, Mikhail Tsvet invented chromatography, an important analytic technique. In 1904, Hantaro Nagaoka proposed an early nuclear model of the atom, where electrons orbit a dense massive nucleus. In 1905, Fritz Haber and Carl Bosch developed the Haber process for making ammonia, a milestone in industrial chemistry with deep consequences in agriculture. The Haber process, or Haber–Bosch process, combined nitrogen and hydrogen to form ammonia in industrial quantities for the production of fertilizer and munitions. The food production for half the world's current population depends on this method for producing fertilizer. Haber, along with Max Born, proposed the Born–Haber cycle as a method for evaluating the lattice energy of an ionic solid. Haber has also been described as the "father of chemical warfare" for his work developing and deploying chlorine and other poisonous gases during World War I.

In 1905, Albert Einstein explained Brownian motion in a way that definitively proved atomic theory. Leo Baekeland invented bakelite, one of the first commercially successful plastics. In 1909, American physicist Robert Andrews Millikan – who had studied in Europe under Walther Nernst and Max Planck – measured the charge of individual electrons with unprecedented accuracy through the oil drop experiment, in which he measured the electric charges on tiny falling water (and later oil) droplets. His study established that any particular droplet's electrical charge is a multiple of a definite, fundamental value—the electron's charge—and thus a confirmation that all electrons have the same charge and mass. Beginning in 1912, he spent several years investigating and finally proving Albert Einstein's proposed linear relationship between energy and frequency, and providing the first direct photoelectric support for the Planck constant. In 1923 Millikan was awarded the Nobel Prize for Physics.
In 1909, S. P. L. Sørensen invented the pH concept and developed methods for measuring acidity. In 1911, Antonius Van den Broek proposed the idea that the elements on the periodic table are more properly organized by positive nuclear charge rather than atomic weight. In 1911, the first Solvay Conference was held in Brussels, bringing together most of the most prominent scientists of the day. In 1912, William Henry Bragg and William Lawrence Bragg proposed Bragg's law and established the field of X-ray crystallography, an important tool for elucidating the crystal structure of substances. In 1912, Peter Debye used the concept of a molecular dipole to describe asymmetric charge distribution in some molecules.

=== Otto Hahn ===

Otto Hahn was a German chemist and a pioneer in the fields of radioactivity and radiochemistry. He played a leading role in the discovery of nuclear fission and established nuclear chemistry as a scientific field. Hahn, Lise Meitner and Fritz Strassmann discovered radioactive isotopes of radium, thorium, protactinium and uranium. He also discovered the phenomena of atomic recoil and nuclear isomerism, and pioneered rubidium–strontium dating. In 1938, Hahn, Meitner and Strassmann discovered nuclear fission. In their second publication on nuclear fission in February 1939, Hahn and Strassmann predicted the existence and liberation of additional neutrons during the fission process, opening up the possibility of a nuclear chain reaction. Hahn received the 1944 Nobel Prize for Chemistry for the discoveries. Nuclear fission was the basis for nuclear reactors and nuclear weapons.

=== Niels Bohr ===